新炭素系材料　電気・光機能性有機材料の高圧合成

• 小島 由継

  (株) 豊田中央研究所

書誌事項

タイトル別名

• High-Pressure Synthesis of Organic Materials for Optoelectronics.

抄録

New cyclic conjugated oligomers were synthesized by reacting diphenyldiacetylene and phenylacetylene under high pressure below 1 GPa. The optical limiting properties of the oligomers were investigated. At low input fluence, the transmittance of the toluene solution obeyed the Beer-Lambert law. Above the threshold of the input fluence, the transmittance decreased with input fluence. The oligomers had an optical limiting property. Furthermore, a unique class of conjugated compounds composed of the derivative of condensed polycyclic aromatic compound with the phenyl group and diphenyldiacetylene oligomer was synthesized with appearance of a gas by annealing of diphenyldiacetylene under elevated pressure. The electrorheological (ER) effect of the suspension of the compound showed the high-temperature working limit to be at least 100°C

収録刊行物

• 高圧力の科学と技術

  高圧力の科学と技術 4 (4), 287-293, 1995

  日本高圧力学会

キーワード

• high pressure
• oligomer
• cyclic
• optical limiting
• diphenyldiacetylene
• phenylacetylene
• electrorheological effect
• condensed polycyclic aromatic compound

詳細情報

• CRID: 1390282679358332416
• NII論文ID: 10002847771
• NII書誌ID: AN10452913
• DOI: 10.4131/jshpreview.4.287
• ISSN: 13481940
• ISSN: 0917639X
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可