高温高圧下の水の構造 [in Japanese] Structure of Water at High Temperatures and Pressures [in Japanese]
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Recent progress in the structural studies of water in the super- and subcritical conditions is reviewed with an emphasis on the hydrogen bonding. The structural characteristics of water at high temperatures and pressures predicted from computer simulations are briefly presented and compared to the results from neutron scattering experiments. The NMR experiments on water in extreme conditions are then described in detail, and the strength of the hydrogen bonding in supercritical water is discussed in terms of the chemical shift. The NMR chemical shift experiments and the computer simulations support the persistence of the hydrogen bonding in supercritical water.
- The Review of High Pressure Science and Technology
The Review of High Pressure Science and Technology 6(1), 16-23, 1997-02-20
The Japan Society of High Pressure Science and Technology