Structure of Water at High Temperatures and Pressures.

• Matubayasi Nobuyuki

  Institute for Chemical Research, Kyoto University

• Nakahara Masaru

  Institute for Chemical Research, Kyoto University

Bibliographic Information

Other Title

• 超臨界水の科学と技術　高温高圧下の水の構造
• コウオン コウアツカ ノ ミズ ノ コウゾウ

Abstract

Recent progress in the structural studies of water in the super- and subcritical conditions is reviewed with an emphasis on the hydrogen bonding. The structural characteristics of water at high temperatures and pressures predicted from computer simulations are briefly presented and compared to the results from neutron scattering experiments. The NMR experiments on water in extreme conditions are then described in detail, and the strength of the hydrogen bonding in supercritical water is discussed in terms of the chemical shift. The NMR chemical shift experiments and the computer simulations support the persistence of the hydrogen bonding in supercritical water.

Journal

• The Review of High Pressure Science and Technology

  The Review of High Pressure Science and Technology 6 (1), 16-23, 1997

  The Japan Society of High Pressure Science and Technology

Keywords

• supercritical water
• structure
• hydrogen bonding
• Proton chemical shift
• computer simulations
• neutron scattering
• X-ray diffractometry

Details

• CRID: 1390282679356916096
• NII Article ID: 10002848502
• NII Book ID: AN10452913
• DOI: 10.4131/jshpreview.6.16
• COI: 1:CAS:528:DyaK2sXit12lsb8%3D
• ISSN: 13481940
• ISSN: 0917639X
• ISSN: http://id.crossref.org/issn/0917639X
• NDL BIB ID: 4150905
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4150905
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed