立方晶B-C-Nの静的高温高圧合成とキャラクタリゼーション Synthesis of Cubic B-C-N under Static High Pressure and Temperature and its Characterization

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Static direct transformation of graphitic BC<SUB>2</SUB>N to cubic forms was discussed on the basis of our results of synthetic experiments and characterizations for the products. The graphitic BC<SUB>2</SUB>N was successfully transformed to diamond-like cubic phases at 7. 7 GPa and 2150-2400°C for 15-60 min using a belt-type high-pressure apparatus. Crystallization of cubic B-C-N compound was confirmed in the products obtained at 2300°C by means of XRD and ATEM. The cubic B-C-N, however, was segregated to diamond and cBN with increasing the synthetic temperature to 2400°C, which was also supported by SEM and AES. The formation behavior seems to provide some conceptions to explore new materials by high-pressure synthesis.

収録刊行物

  • 高圧力の科学と技術 = The Review of high pressure science and technology  

    高圧力の科学と技術 = The Review of high pressure science and technology 6(4), 222-229, 1997-11-01 

    The Japan Society of High Pressure Science and Technology

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各種コード

  • NII論文ID(NAID)
    10002848838
  • NII書誌ID(NCID)
    AN10452913
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    0917639X
  • NDL 記事登録ID
    4367806
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z17-1589
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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