High Pressure--a Useful Parameter for Catalysis? (特集 有機反応と高圧力) High Pressure - a Useful Parameter for Catalysis?
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The scope and limitation of high pressure for the catalysis of organic reactions is evaluated. This article focuses on Lewis acid (cycloadditions, epoxide openings, Horner-Wadsworth-Emmons reactions) and palladium catalyzed (Heck-reaction, [3+2] cycloadditions) reactions. Aspects of reactivity (turnover frequencies and turnover rates) as well as selectivity (chemoselectivity, regioselectivity, diastereo- and enantioselectivity) under the influence of pressure will be discussed.
- The Review of High Pressure Science and Technology
The Review of High Pressure Science and Technology 8(2), 111-120, 1998-05-20
The Japan Society of High Pressure Science and Technology