B-C-N系物質の低圧相と高圧相の合成研究 Syntheses of Low-Pressure and High-Pressure Phases in the B-C-N System

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This article reviews recent progress in the syntheses of B-C-N ternary materials. A number of B-C-N graphites of various stoichiometry have been synthesized via chemical vapor deposition and pyrolysis of precursors. One of the typical compositions, BC<SUB>2</SUB>N, has been relatively well-characterized, revealing that it is a genuine B-C-N compound with a semiconductive nature with a bandgap around 2 eV. Static and dynamic compressions on the B-C-N graphites have been conducted to explore the phase relationship and stability of B-C-N high-pressure phases. The results from these studies can systematically be understood by the fact that segregation into diamond and cBN is thermodynamically favored rather than formation of a B-C-N diamond-like compound.

収録刊行物

  • 高圧力の科学と技術 = The Review of high pressure science and technology  

    高圧力の科学と技術 = The Review of high pressure science and technology 8(3), 177-184, 1998-08-20 

    The Japan Society of High Pressure Science and Technology

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各種コード

  • NII論文ID(NAID)
    10002849317
  • NII書誌ID(NCID)
    AN10452913
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    0917639X
  • NDL 記事登録ID
    4546294
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z17-1589
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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