電子移動反応と高圧化学 Electron Transfer Reactions at Elevated Pressures

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著者

    • 高木 秀夫 TAKAGI Hiedo
    • 名古屋大学大学院理学研究科物質理学専攻無機・分析化学大講座 Inorganic and Analytical Chemistry Division, Department of Chemistry and Physics, Graduate School of Sciences, Nagoya University

抄録

The theory of outer-sphere electron tranfer processes has been developed by many scientists since the first publication by Libby in 1952 referring to the role of the solvent. After the establishment of Marcus Theory, the electron transfer reactions have been analysed on the basis of activation free energy, provided that the inner-sphere and outer-sphere changes are concerted. However, this approach was proved to be rather inaccurate because of the uncertainties in the estimation of the inner-sphere contribution to the activation free energy. A recent development of the analyses based on the volume profiles of reactions, however, proved that the more accurate interpretation of the outer-sphere electron transfer processes is possible as the uncertainty related to the inner-sphere contribution diminishes. Theoretical treatment and the application of the "volume analysis" to various outer-sphere reactions are summarized in this review, together with an application of the volume analysis to the "Gated" electron transfer processes.

収録刊行物

  • 高圧力の科学と技術 = The Review of high pressure science and technology  

    高圧力の科学と技術 = The Review of high pressure science and technology 8(3), 193-208, 1998-08-20 

    The Japan Society of High Pressure Science and Technology

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各種コード

  • NII論文ID(NAID)
    10002849367
  • NII書誌ID(NCID)
    AN10452913
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    0917639X
  • NDL 記事登録ID
    4546296
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z17-1589
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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