Electron Transfer Reactions at Elevated Pressures.

• Takagi Hideo

  Graduate School of Sciences, Nagoya University

Bibliographic Information

Other Title

• 電子移動反応と高圧化学
• デンシ イドウ ハンノウ ト コウアツ カガク

Abstract

The theory of outer-sphere electron tranfer processes has been developed by many scientists since the first publication by Libby in 1952 referring to the role of the solvent. After the establishment of Marcus Theory, the electron transfer reactions have been analysed on the basis of activation free energy, provided that the inner-sphere and outer-sphere changes are concerted. However, this approach was proved to be rather inaccurate because of the uncertainties in the estimation of the inner-sphere contribution to the activation free energy. A recent development of the analyses based on the volume profiles of reactions, however, proved that the more accurate interpretation of the outer-sphere electron transfer processes is possible as the uncertainty related to the inner-sphere contribution diminishes. Theoretical treatment and the application of the "volume analysis" to various outer-sphere reactions are summarized in this review, together with an application of the volume analysis to the "Gated" electron transfer processes.

Journal

• The Review of High Pressure Science and Technology

  The Review of High Pressure Science and Technology 8 (3), 193-208, 1998

  The Japan Society of High Pressure Science and Technology

Keywords

• electron transfer
• theory and application
• mechanism
• activation volume
• reaction volume
• elevated pressure

Details

• CRID: 1390001204380579072
• NII Article ID: 10002849367
• NII Book ID: AN10452913
• DOI: 10.4131/jshpreview.8.193
• ISSN: 13481940
• ISSN: 0917639X
• NDL BIB ID: 4546296
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4546296
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed