Synthesis, Stereochemistry, and Thermolysis of β-Aminoalkylboranes

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著者

    • YAMASHITA Naoko
    • Department of Chemistry, Graduate School of Science, The University of Tokyo
    • OKAZAKI Renji
    • Department of Chemistry, Graduate School of Science, The University of Tokyo

抄録

<I>erythro</I>- and <I>threo</I>-β-Amino boranes Mes<SUB>2</SUB>BCHMeCHPhNHPh were synthesized by the reaction of Mes<SUB>2</SUB>BCHMeLi with <I>N</I>-benzylideneaniline. The stereochemistry was determined by chemical derivation into the corresponding cycic carbanates via β-amino alcohols. Their thermolysis gave a mixture of the corresponding (<I>E</I>)-enamine and its tautomer, (<I>E</I>)-imine, in sharp contrast to that of β-hydroxy boranes giving the olefins.

収録刊行物

  • Chemistry letters

    Chemistry letters 1996(3), 213-214, 1996-03-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10003739115
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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