Water-Etha nol Clusters at the Liquid Surface under Atmospheric Pressure Observed by Liquid Ionization Mass Spectrometry

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著者

    • TSUCHIYA Masahiko
    • Department of Physical Chemistry, Faculty of Engineering, Yokohama National University
    • LI Yaming
    • Department of Physical Chemistry, Faculty of Engineering, Yokohama National University
    • SHIRASAKA Jingo
    • Department of Physical Chemistry, Faculty of Engineering, Yokohama National University
    • KANEKO Takeo
    • Department of Physical Chemistry, Faculty of Engineering, Yokohama National University

抄録

By controlling the flow rate of a sample solution, information about clusters existing at the liquid surface were obtained by liquid ionization (LI) mass spectrometry. The relative abundances of binary cluster ions, (C<SUB>2</SUB>H<SUB>5</SUB>OH)<SUB>m</SUB>(H<SUB>2</SUB>O)<SUB>n</SUB>H<SUP>+</SUP>, with large m and n increased with the flow rate, while the abundances of ethanol cluster ions, (C<SUB>2</SUB>H<SUB>5</SUB>OH)<SUB>m</SUB>H<SUP>+</SUP>, increased by decreasing the flow rate. Molar ratios of water to ethanol observed were much higher than those observed by other methods.

収録刊行物

  • Chemistry letters

    Chemistry letters 1996(3), 229-230, 1996-03-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10003739224
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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