Analysis of Dodecahedral Voids in Single-Quasicrystalline Al–Pd–Mn by Scanning Electron Microscopy and Auger Electron Spectroscopy

  • Suzuki S.
    Institute for Advanced Materials Processing, Tohoku University
  • Waseda Y.
    Institute for Advanced Materials Processing, Tohoku University
  • Urban K.
    Institute for Advanced Materials Processing, Tohoku University

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  • Analysis of Dodecahedral Voids in Singl
  • Analysis of Dodecahedral Voids in Single-Quasicrystalline Al–Pd–Mn by Scanning Electron Microscopy and Auger Electron Spectroscopy

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Abstract

Scanning electron microscopy and microprobe Auger electron spectroscopy were used for characterizing the morphology and the surface composition of voids in the bulk of icosahedral Al–Pd–Mn single-quasicrystals. The samples were prepared by in-situ cleavage fracture in the ultra-high vacuum. The void images could be explained on the basis of an irregular dodecahedral shape. The void facets were parallel to five-fold quasicrystal lattice planes. The surfaces of the voids grown under close-to-equilibrium conditions during the cooling of the quasicrystal were depleted in Mn and enriched in Pd with respect to the bulk.

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