ピエゾ電気収着法によるポリマー中への高圧ガスの溶解度の測定および相関 CO2+PVAc系およびCO2PBMA系

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タイトル別名
  • Solubility measurements of gas in polymer by the piezoelectric quartz sorption method at high pressures and its correlation. CO2+PVAc and CO2+PBMA systems.
  • ピエゾ デンキ シュウチャクホウ ニ ヨル ポリマーチュウ エ ノ コウアツ
  • CO<SUB>2</SUB>+ PVAc and CO<SUB>2</SUB> +PBMA systems
  • CO<SUB>2</SUB>+PVAc系およびCO<SUB>2</SUB>+PBMA系

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The solubilities of carbon dioxide in poly (vinyl acetate) and poly (butyl methacrylate) were measured by the piezoelectric-quartz sorption method at fixed temperatures of 313.2K, 333.2K and 353.2K, and pressures up to 10MPa. Pressure dependence of the crystal frequency was investigated experimentally, and no reference crystal was used in this work. This is a feature of our method that differs from other work. Furthermore, the solubility data were correlated by Sanchez and Lacombe's EOS and Kumar's EOS. It was found that Kumar's EOS is satisfactorily applicable to these systems.

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