Electrocatalytic Hydrogenation of Olefins Using Palladium Metal Microparticles Deposited on Viologen Film-coated Graphite Felt

• KASHIWAGI Yoshitomo

  Graduate School of Pharmaceutical Sciences, Tohoku University

• SHIBAYAMA Norihiko

  Graduate School of Pharmaceutical Sciences, Tohoku University

• ANZAI Jun-ichi

  Graduate School of Pharmaceutical Sciences, Tohoku University

• OSA Tetsuo

  Graduate School of Pharmaceutical Sciences, Tohoku University

抄録

Palladium (Pd) metal microparticles were deposited in a viologen-containing polymer layer on the surface of a graphite felt electrode. The Pd-deposited electrode is effective for the electrocatalytic hydrogenation of the carbon-carbon double bond part of alkyl olefins (1-hexene, 1-decene, cis-2-penetene), conjugated enones (2-cyclohexene-1-one, 4-isopropyl-2-cyclohexene-1-one, 3,5,5-trimetyl-2-cyclohexene-1-one), styrene, and trans-stilbene with 100% selectivity.

収録刊行物

• Electrochemistry

  Electrochemistry 68 (1), 42-45, 2000-01-05

  公益社団法人　電気化学会

キーワード

• Electrocatalytic Hydrogenation
• Viologen Film-coated Graphite Felt Electrode
• Pd-deposited

詳細情報

• CRID: 1390001277391050112
• NII論文ID: 10004274022
• NII書誌ID: AN00151637
• DOI: 10.5796/electrochemistry.68.42
• ISSN: 21862451
• ISSN: 13443542
• ISSN: http://id.crossref.org/issn/13443542
• NDL書誌ID: 4952635
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4952635
• Web Site: https://www.jstage.jst.go.jp/article/electrochemistry/68/1/68_42/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用可