Facilitated Ion-Transfer of a Hydrophobic Tetraalkylammonium Ion in Nitrobenzene to Aqueous Phase by Humic Acid

  • Keiko Ichihashi
    Graduate School of Science, Osaka City UniversitySugimoto, Sumiyoshi-ku, Osaka
  • Akio Ichimura
    Graduate School of Science, Osaka City UniversitySugimoto, Sumiyoshi-ku, Osaka
  • Hidekazu Doe
    Graduate School of Science, Osaka City UniversitySugimoto, Sumiyoshi-ku, Osaka
  • Kiyoshi Teranishi
    Public Health Institute of Hyogo PrefectureArata-cho, Hyogo-ku, Kobe

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<jats:title>Abstract</jats:title> <jats:p>Ion transfer at an interface of organic nitrobenzene and aqueous phases was polarographically studied in the presence of humic acid using an ascending aqueous electrode. The transfer of hydrophobic tetraheptylammonium cation as a supporting electrolyte ion in nitrobenzene to the aqueous phase was greatly facilitated by the incorporation into the micelle-like humic acid aggregates formed around CMC of humic acid.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 28 (5), 383-384, 1999-05-01

    Oxford University Press (OUP)

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