New Positive - Type Photosensitive Poly(phenylene ether): Poly(2 - hydroxy - 6 - methylphenol - co - 2, 6 - dimethylphenol) with Diazonaphthoquinone

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著者

    • TAKESHI Kazumasa
    • Department of Human Sensing and Functional Sensor Engineering, Graduate School of Engineering, Yamagata University
    • OKUYAMA Ken-ichi
    • Department of Human Sensing and Functional Sensor Engineering, Graduate School of Engineering, Yamagata University
    • OHBA Yoshihiro
    • Department of Human Sensing and Functional Sensor Engineering, Graduate School of Engineering, Yamagata University
    • UEDA Mitsuru
    • Department of Human Sensing and Functional Sensor Engineering, Graduate School of Engineering, Yamagata University

抄録

A positive working thermally stable and photosensitive polymer based on poly(2-hydroxy-6-methylphenol-<I>co</I>-2,6-dimethyl phenol) (PHP-MP) and 2,3,4-tris[2-diazo-1(2H)-naphthalenone-4-sulfonyloxy] benzophenone (D4SB) as a photoreactive compound has been developed. The copolymer PHP-MP was prepared by oxidative coupling polymerization of 2-(tetrahydropyran-2-yl)oxy-6-methylphenol with 2,6-dimethylphenol, followed by acid treatment. The PHP-MP film showed excellent transparency above 300 nm. A clear positive pattern was obtained when it was exposed to 365 nm light, followed by developing with a 2.38% aqueous tetramethylammonium hydroxide (TMAH) solution at 25 °C.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(5), 393-394, 1999-05-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004341391
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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