Novel Dihydridoruthenium(II) Complexes with Chelating Diphosphine Ligands, RuH_2(CO)(diphosphine)(PPh_3)(diphosphine = dppe, dppp, dppb, and dppf)

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著者

    • KAWANO Hiroyuki
    • Graduate School of Marine Science and Engineering, Nagasaki University
    • TANAKA Rie
    • Department of Applied Chemistry, Faculty of Engineering, Nagasaki University
    • FUJIKAWA Tomoko
    • Department of Applied Chemistry, Faculty of Engineering, Nagasaki University
    • HIRAKI Katsuma
    • Department of Applied Chemistry, Faculty of Engineering, Nagasaki University
    • ONISHI Masayoshi
    • Department of Applied Chemistry, Faculty of Engineering, Nagasaki University

抄録

Ligand exchange of [RuH<SUB>2</SUB>(CO)(PPh<SUB>3</SUB>)<SUB>3</SUB>] with some diphosphine ligands affords a series of [RuH<SUB>2</SUB>(CO)(diphosphine)(PPh<SUB>3</SUB>)] (diphosphine = dppe, dppp, dppb, and dppf). The X-ray structure analysis of [RuH<SUB>2</SUB>(CO)(dppp)(PPh<SUB>3</SUB>)] reveals its distorted octahedral structure. The diphosphine ligand complexes react with styrene to generate ruthenium(0) species, which successively proceed with the intramolecular C-H addition to give the cyclometallated aryl(hydrido)ruthenium(II) species.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(5), 401-402, 1999-05-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004341446
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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