Control of Reductive Elimination and Acidolysis of Diarylnickel(II) Complexes by the Kind of Bronsted Acid and the Presence of Oxygen
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Reaction of NiAr<SUB>2</SUB>(bpy) (Ar = electron withdrawing aryl group, bpy = 2,2′-bipypridyl) with Brønsted acids leads to reductive elimination of Ar-Ar from NiAr<SUB>2</SUB>(bpy). The reaction also causes acidolysis of the Ni complex depending on the kind of the acid and reaction conditions.
- Chemistry Letters
Chemistry Letters 1999(5), 419-420, 1999-05-05
The Chemical Society of Japan