Syntheses of Novel Cyclotriveratrylenophane Capsules and Their Supramolecular Complexes of Fullerenes

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  • Hiroshi Matsubara
    Department of Chemistry, College of Integrated Arts and Sciences, Osaka Prefecture UniversitySakai, Osaka
  • Shin-ya Oguri
    Department of Chemistry, College of Integrated Arts and Sciences, Osaka Prefecture UniversitySakai, Osaka
  • Kaori Asano
    Department of Chemistry, College of Integrated Arts and Sciences, Osaka Prefecture UniversitySakai, Osaka
  • Koji Yamamoto
    Department of Chemistry, College of Integrated Arts and Sciences, Osaka Prefecture UniversitySakai, Osaka

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<jats:title>Abstract</jats:title> <jats:p>Cyclotriveratrylenophanes were synthesized and their inclusion abilities for fullerenes were examined by UV spectroscopy. From the spectra, the association constants were determined using Rose and Drago method. Cyclotriveratrylene hosts showed shape-selective properties and large association constants up to 19400 ± 110 dm3mol−1 for C60 and 26500 ± 260 dm3mol−1 for C70</jats:p>

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  • Chemistry Letters

    Chemistry Letters 28 (5), 431-432, 1999-05-01

    Oxford University Press (OUP)

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