Assembly of a Tetranuclear Mixed-Valence Manganese(II,III) Complex from a Binuclear Manganese(II) Complex by Photo-Irradiation

  • Shouichi Tomida
    Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga UniversitySaga
  • Hideaki Matsushima
    Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga UniversitySaga
  • Masayuki Koikawa
    Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga UniversitySaga
  • Tadashi Tokii
    Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga UniversitySaga

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Abstract

<jats:title>Abstract</jats:title> <jats:p>A tetranuclear mixed-valence manganese(II,III) complex, [Mn2(O)(Ph2MeCCOO)2(phen)2]2(PF6)2·10H2O (2), has been assembled from a binuclear manganese(II) complex, [Mn(Ph2MeCCOO)(phen)2]2(PF6)2·2MeCN (1) by use of a photo-induced oxidation reaction.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 28 (5), 437-438, 1999-05-01

    Oxford University Press (OUP)

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