高品質単分子膜におけるナノメートル領域の分子素子特性

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タイトル別名
  • Nanometer-scale Unimonolayer Device Properties of High-quality Monolayer Film
  • コウヒンシツタンブンシマク ニ オケル ナノメートル リョウイキ ノ ブンシ

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We prepared high-quality monolayer Langmuir-Blodgett films using a novel molecule C37H40N404 synthesized by us. This molecule is the long-chain alkyl derivative which has dinitrobenzene moiety (acceptor subunit) and dihydrophenazine (donor subunit) bridged by a methylene group with constant distance and bond angle. It behaves as unimolecular device with the control of the potential between donor and acceptor subunits. We transferred the monolayer film onto a mica plate and succeeded in getting molecular images by AFM. Furthermore the monolayer was transferred onto Au (111) and manometer-scale rectifying or semiconducting characteristics were successfully obtained by using AFM I-V technique.

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