Synthesis of New Ni-Complexes with a Chalcogen Donor Ligand and Cyano Groups
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New Ni-complexes [C<SUB>4</SUB>H<SUB>9</SUB>)<SUB>4</SUB>N]<SUB>n</SUB>[Ni(C<SUB>8</SUB>H<SUB>4</SUB>S<SUB>8</SUB>)(CN)<SUB>2</SUB>](n = 1, 2) have been synthesized and characterized in order to understand a change in the chemical property and electronic structure of bis(ethylenedihthio)tetrathiafulvalene molecule by introducing a transition metal with small bridging ligands in place of an ethylene group. The effect of such a metalation has turned out to be larger than that of any alkylation.
- Chemistry Letters
Chemistry Letters 1998(8), 723-724, 1998-08-05
The Chemical Society of Japan