Synthesis of New Ni-Complexes with a Chalcogen Donor Ligand and Cyano Groups

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著者

    • NAITO Toshio
    • Division of Chemistry, Graduate School of Science, Hokkaido University
    • INABE Tamotsu
    • Division of Chemistry, Graduate School of Science, Hokkaido University

抄録

New Ni-complexes [C<SUB>4</SUB>H<SUB>9</SUB>)<SUB>4</SUB>N]<SUB>n</SUB>[Ni(C<SUB>8</SUB>H<SUB>4</SUB>S<SUB>8</SUB>)(CN)<SUB>2</SUB>](n = 1, 2) have been synthesized and characterized in order to understand a change in the chemical property and electronic structure of bis(ethylenedihthio)tetrathiafulvalene molecule by introducing a transition metal with small bridging ligands in place of an ethylene group. The effect of such a metalation has turned out to be larger than that of any alkylation.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1998(8), 723-724, 1998-08-05 

    The Chemical Society of Japan

参考文献:  4件

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各種コード

  • NII論文ID(NAID)
    10004483980
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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