Synthesis of (-)-Gleenol via C-H Insertion Reaction of Alkylidenecarbene

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著者

    • OHIRA Susumu
    • Department of Biological Chemistry, Faculty of Science, Okayama University of Science
    • YOSHIHARA Naoya
    • Department of Biological Chemistry, Faculty of Science, Okayama University of Science
    • HASEGAWA Taisuke
    • Department of Biological Chemistry, Faculty of Science, Okayama University of Science

抄録

A spiro sesquiterpene alcohol, (−)-gleenol (1) was synthesized from (−)-l-menthol in 16 steps, using the C-H insertion reaction of the alkylidenecarbene as the key step. The absolute configuration of (−)-1 was determined to be 1S, 6R, 7S, 10R.

収録刊行物

  • Chemistry letters

    Chemistry letters 1998(8), 739-740, 1998-08-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004484082
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  CJP引用  J-STAGE 
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