Synthesis, Structure, Tautomerism, and 1,4-Dipolar Cycloaddition of Thermally Stable, Crystalline 1,4-Dipoles

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著者

    • NAKAYAMA Juzo
    • Department of Chemistry, Faculty of Science, Saitama University
    • KITAHARA Taku
    • Department of Chemistry, Faculty of Science, Saitama University
    • OTANI Takashi
    • Department of Chemistry, Faculty of Science, Saitama University
    • ISHII Akihiko
    • Department of Chemistry, Faculty of Science, Saitama University

抄録

Phenyl isothiocyanate reacted with 2-methylene-1,3-dimethylimidazolidines to give thermally stable, crystalline adducts that possess an inner salt (1,4-dipolar) structure or its tautomeric thioamide structure depending on substituent on the methylene part. Tautomerism between the 1,4-dipolar form and the thioamide form, X-ray diffraction analysis, and 1,4-dipolar cycloaddition with DMAD of these adducts are reported.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1998(9), 887-888, 1998-09-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004485202
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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