Ruthenium-Catalyzed Reactions of Acyclic α,β-Enones with Olefins and Their Reaction Mechanisms

DOI PDF 被引用文献11件 参考文献25件
  • Taisuke Sato
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Fumitoshi Kakiuchi
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Naoto Chatani
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Shinji Murai
    Department of Applied Chemistry, Faculty of Engineering, Osaka University

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<jats:title>Abstract</jats:title> <jats:p>The reaction of 4,4-dimethyl-5-phenyl-4-peneten-3-one with styrene (2) using Ru(H)2(CO)(PPh3)3 as the catalyst gave the stereochemically retained product. In the case of 2,2-dimethyl-4-hexen-3-one, the stereochemically inverted branched product was obtained. These results are consistent with two different reaction pathways operating, i.e. one involving a direct C-H bond cleavage and the other, a pathway involving hydrometallation.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 27 (9), 893-894, 1998-09-01

    Oxford University Press (OUP)

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