A Novel Discrete d-f Heterobinuclear Complex Designed from Tetrahedrally Distorted [Cu (salabza)] (H_2salabza : N,N'-Bis (salicylidene)-2-aminobenzylamine) and [Gd (hfac)_3]

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著者

    • SASAKI Miwa
    • Department of Material and Biological Chemisty, Faculty of Science, Yamagata University
    • HORIUCHI Hiroaki
    • Department of Material and Biological Chemisty, Faculty of Science, Yamagata University
    • KUMAGAI Motoko
    • Department of Material and Biological Chemisty, Faculty of Science, Yamagata University
    • SAKAMOTO Masatomi
    • Department of Material and Biological Chemisty, Faculty of Science, Yamagata University
    • SAKIYAMA Hiroshi
    • Department of Material and Biological Chemisty, Faculty of Science, Yamagata University
    • SADAOKA Yoshihiko
    • Department of Materials Science and Engineering, Faculty of Engineering, Ehime University
    • OHBA Masaaki
    • Department of Chemistry, Faculty of Science, Kyushu University
    • OKAWA Hisashi
    • Department of Chemistry, Faculty of Science, Kyushu University

抄録

Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)<SUB>3</SUB>], was synthesized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)<SUB>3</SUB>]·2H<SUB>2</SUB>O, where H<SUB>2</SUB>salabza and Hhfac denote N,N′-bis(salicylidene)-2-aminobenzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectively. Structural analysis revealed that the complex has the long intermolecular metal-metal distances enough to be regarded as a discrete one.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1998(9), 911-912, 1998-09-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004485382
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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