Synthesis of 2-Aminomethylpyridene-appended [60]Fullerenes. On the Difference in the Metal-binding Properties between 5,6-Open and 6,6-Closed Isomers

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  • Atsushi Ikeda
    Department of Chemical Science & Technology, Faculty of Engineering, Kyushu University
  • Chie Fukuhara
    Department of Chemical Science & Technology, Faculty of Engineering, Kyushu University
  • Seiji Shinkai
    Department of Chemical Science & Technology, Faculty of Engineering, Kyushu University

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<jats:title>Abstract</jats:title> <jats:p>Two 2-aminomethylpyridine-appended [60]fullerenes (1) with the 5,6-open and the 6,6-closed structure were synthesized in order to examine the influence of the structural difference on the metal-binding ability. Both compounds could form the 1:1 complex with Ag+ but the Kass for 5,6-1 was larger by more than two orders of magnitude than that for 6,6-1.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 27 (9), 915-916, 1998-09-01

    Oxford University Press (OUP)

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