Toward Synthesis of Novel C-glycoprotein from Human RNase; Unexpected Stereochemistry of Epoxide Opening Reaction by Organolithium Reagents in the Presence of Lewis Acid

• Shino Manabe

  The Institute of Physical and Chemical Research(RIKEN)

• Yukishige Ito

  The Institute of Physical and Chemical Research(RIKEN)

• Tomoya Ogawa

  The Institute of Physical and Chemical Research(RIKEN)

Abstract

A nucleophilic attack reaction to 1,2-anhydro-β-D-manno-pyranose by indole derived organolithium reagents in the presence of BF3·OEt2 afforded isomers of C-aryl glycoside corresponds to the basic skeleton of C-linked mannosyl tryptophan, which is recently identified in human RNase.

Journal

• Chemistry Letters

  Chemistry Letters 27 (9), 919-920, 1998-09-01

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360565169062993280
• NII Article ID: 10004485434
• NII Book ID: AA00603318
• DOI: 10.1246/cl.1998.919
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/27/9/919/56072582/cl.1998.919.pdf
• Data Source:
  • Crossref
  • CiNii Articles