Tribenzo-1,4,5,8,9,12-hexathiatriphenylene Dication and Dibenzo-1,4,5,8-tetrathiaphenanthrene Dication

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著者

    • NAKAI Takeo
    • Department of Chemistry, Graduate School of Science, Osaka City University
    • KOZAKI Masatoshi
    • Department of Chemistry, Graduate School of Science, Osaka City University
    • SATO Kazunobu
    • Department of Chemistry, Graduate School of Science, Osaka City University
    • SHIOMI Daisuke
    • Department of Chemistry, Graduate School of Science, Osaka City University
    • TAKUI Takeji
    • Department of Chemistry, Graduate School of Science, Osaka City University
    • ITOH Koichi
    • Department of Material Science, Graduate School of Science, Osaka City University
    • OKADA Keiji
    • Department of Chemistry, Graduate School of Science, Osaka City University

抄録

Tribenzo-1,4,5,8,9,12-hexathiatriphenylene dication (1<SUP>2+</SUP>) and dibenzo-1,4,5,8-tetrathiaphenanthrene dication (2<SUP>2+</SUP>) were generated in concentrated sulfuric acid. Their zero-field splitting parameters were determined as D = 0.012 cm<SUP>−1</SUP>, E ≈ 0.00 cm<SUP>−1</SUP> for 1<SUP>2+</SUP>, and D = 0.012 cm<SUP>−1</SUP>, E ≈ 0.00 cm<SUP>−1</SUP> for 2<SUP>2+</SUP>. The dication 1<SUP>2+</SUP> was found to be a triplet in the ground state, whereas 2<SUP>2+</SUP> to be a singlet ground state with the singlet-triplet energy gap of −35 ± 2 J/mol.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1998(9), 933-934, 1998-09-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004485562
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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