The First Isolation and Structural Analysis of Chalcogenocarboxylato Samarium Complexes, [(RCOS)_3Sm(thf)_2] and [Na(thf)_4] [Sm(RCSS)_4]; The Alkali Metal Salt-Like Reaction and the Insertion Reaction of Imine to the Sm-S Bond

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著者

    • KANDA Takahiro
    • Department of Chemistry, Faculty of Engineering, Gifu University
    • IBI Mitsuo
    • Department of Chemistry, Faculty of Engineering, Gifu University
    • KATO Shinzi
    • Department of Chemistry, Faculty of Engineering, Gifu University

抄録

The first chalcogenocarboxylato lanthanid complexes, [(RCOS)<SUB>3</SUB>Sm(thf)<SUB>2</SUB>] and [Na(thf)<SUB>4</SUB>][Sm(RCSS)<SUB>4</SUB>](R = 4-MeC<SUB>6</SUB>H<SUB>4</SUB>) were isolated and characterized crystallographically. They exhibit an alkali metal salt-like reaction such as S-esterification and an insertion reaction of C=N to the Sm-S bond.

収録刊行物

  • Chemistry letters

    Chemistry letters 1998(9), 957-958, 1998-09-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004485722
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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