Synthesis of Carboxylic Acids through the Formation of C - C Bond between Saturated Hydrocarbons and CO in the Presence of Mg/K_2S_2O_8/TFA System

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著者

    • ASADULLAH Mohammad
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
    • KITAMURA Tsugio
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
    • FUJIWARA Yuzo
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University

抄録

Magnesium powder (Mg) promoted the carboxylation reaction of saturated hydrocarbons with carbon monoxide (CO) in the presence of potassium peroxodisulfate (K<SUB>2</SUB>S<SUB>2</SUB>O<SUB>8</SUB>) in trifluoroacetic acid (TFA) to yield the corresponding carboxylic acids and alkyl trifluoroacetates. About 80% conversion of cyclohexane was achieved when 5 mmol of magnesium, 5 mmol of potassium peroxodisulfate, 3 mL of TFA, 1 mmol of cyclohexane, 50 atm of CO were used at 80 °C for 30 h.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(6), 449-450, 1999-06-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004485797
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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