Synthesis of Carboxylic Acids through the Formation of C–C Bond between Saturated Hydrocarbons and CO in the Presence of Mg/K2S2O8/TFA System

• Asadullah Mohammad

  Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University

• Kitamura Tsugio

  Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University

• Fujiwara Yuzo

  Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University

書誌事項

タイトル別名

• Synthesis of Carboxylic Acids through the Formation of C–C Bond between Saturated Hydrocarbons and CO in the Presence of Mg/K<SUB>2</SUB>S<SUB>2</SUB>O<SUB>8</SUB>/TFA System

抄録

Magnesium powder (Mg) promoted the carboxylation reaction of saturated hydrocarbons with carbon monoxide (CO) in the presence of potassium peroxodisulfate (K₂S₂O₈) in trifluoroacetic acid (TFA) to yield the corresponding carboxylic acids and alkyl trifluoroacetates. About 80% conversion of cyclohexane was achieved when 5 mmol of magnesium, 5 mmol of potassium peroxodisulfate, 3 mL of TFA, 1 mmol of cyclohexane, 50 atm of CO were used at 80 °C for 30 h.

収録刊行物

• Chemistry Letters

  Chemistry Letters 28 (6), 449-450, 1999

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204576721792
• NII論文ID: 10004485797
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.1999.449
• COI: 1:CAS:528:DyaK1MXjs1Ojt7s%3D
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/28/6/449/56076884/cl.1999.449.pdf
• 本文言語コード: en
• データソース種別:
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• 抄録ライセンスフラグ: 使用不可