Chain Compound of Mixed - Valent Ruthenium Dimers Linked by Hydrogen - Bonding between the Axially Coordinated Nitronyl Nitroxide and Water Molecules

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著者

    • HANDA Makoto
    • Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University
    • HIROMITSU Ichiro
    • Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University
    • KASUGA Kuninobu
    • Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University

抄録

An adduct of ruthenium(II,III) dimer with nitronyl nitroxide, [{Ru<SUB>2</SUB>(O<SUB>2</SUB>CCMe<SUB>3</SUB>)<SUB>4</SUB>(nitme)<SUB>2</SUB>}{Ru<SUB>2</SUB>(O<SUB>2</SUB>CCMe<SUB>3</SUB>)<SUB>4</SUB>(H<SUB>2</SUB>O)<SUB>2</SUB>}]<SUB><I>n</I></SUB>(BF<SUB>4</SUB>)<SUB>2<I>n</I></SUB> (nitme = 2,4,4,5,5-pentamethyl-4,5-dihydro-1<I>H</I>-imidazolyl-1-oxyl 3-oxide), which has a chain structure formed by hydrogen bonds between the axial nitme and water molecules, has been prepared and characterized by the X-ray crystallography, magnetic susceptibility, and EPR measurements.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(6), 453-454, 1999-06-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004485837
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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