A Unique Chelating Effect of Sc(OTf)_3 to Organofluorine Compounds

この論文にアクセスする

この論文をさがす

著者

    • KAJIRO Hiroshi
    • Research Laboratory of Resources Utilization, Tokyo Institute of Technology
    • MORI Atsunori
    • Research Laboratory of Resources Utilization, Tokyo Institute of Technology
    • NISHIHARA Yasushi
    • Research Laboratory of Resources Utilization, Tokyo Institute of Technology
    • HIYAMA Tamejiro
    • Research Laboratory of Resources Utilization, Tokyo Institute of Technology

抄録

The scandium trifluoromethanesulfonate-catalyzed cleavage of acetate bearing two or three fluorine atoms at a position β to an acetoxy group proceeds exceptionally rapidly. The high efficiency of the hydrolysis is caused by a chelating effect of scandium with the fluorine atoms and an acetate moiety.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(6), 459-460, 1999-06-05

    The Chemical Society of Japan

参考文献:  24件中 1-24件 を表示

  • <no title>

    FILLER R.

    Biomedical Aspects of Fluorine Chemistry, 1982

    被引用文献9件

  • <no title>

    BANKS R. E.

    Preparation, Properties, and Industrial Applications of Organofluorine Compounds, 1982

    被引用文献3件

  • <no title>

    O'DONNELL T. A.

    The Chemistry of Fluorine, 1975

    被引用文献1件

  • <no title>

    OOI T.

    Chem. Lett. 1998, 403

    被引用文献1件

  • <no title>

    QUIAN C. P.

    J. Am. Chem. Soc. 112, 4602, 1990

    被引用文献1件

  • <no title>

    OOI T.

    Chem. Lett. 1998, 817

    被引用文献3件

  • <no title>

    OOI T.

    J. Am. Chem. Soc. 119, 5754, 1997

    被引用文献9件

  • <no title>

    POSNER G. H.

    Tetrahedron Lett. 26, 1823, 1985

    被引用文献2件

  • <no title>

    HANAMOTO T.

    J. Org. Chem. 55, 4969, 1990

    被引用文献5件

  • <no title>

    NICOLAOU K. C.

    J. Chem. Soc., Chem. Commun. 1984, 1153

    被引用文献1件

  • <no title>

    PLETINO H.

    Chem. Rev. 97, 3363, 1997

    被引用文献1件

  • <no title>

    MURPHY E. F.

    Chem. Rev. 97, 3425, 1997

    被引用文献1件

  • <no title>

    YAMAZAKI T.

    J. Synth. Org. Chem. Jpn. 54, 665, 1996

    被引用文献2件

  • <no title>

    SMITH J. W.

    The Chemistry of the Carbon-Halogen Bond Part I, 292-297, 1973

    被引用文献1件

  • <no title>

    ISHIHARA K.

    J. Org. Chem. 61, 4560, 1996

    被引用文献18件

  • <no title>

    YANADA R.

    Synlett 1995, 1261

    被引用文献4件

  • <no title>

    YASHIRO M.

    J. Chem. Soc., Chem. Commun. 1994, 1757

    被引用文献4件

  • <no title>

    INANAGA J.

    J. Chem. Soc., Chem. Commun. 1993, 1090

    被引用文献15件

  • <no title>

    KOMIYAMA M.

    J. Chem. Soc., Chem. Commun. 1992, 640

    被引用文献12件

  • <no title>

    MARSHMAN R. W.

    Aldrichimica Acta 28, 77, 1995

    被引用文献1件

  • <no title>

    KOBAYASHI S.

    Eur. J. Org. Chem. 1999, 15

    被引用文献11件

  • <no title>

    KAJIRO H.

    Synlett 1998, 51

    DOI 被引用文献3件

  • <no title>

    KAJIRO H.

    Tetrahedron Lett. 40, 1689, 1999

    DOI 被引用文献2件

  • <no title>

    SHULL B. K.

    J. Am. Chem. Soc. 118, 11690, 1996

    DOI 被引用文献2件

各種コード

  • NII論文ID(NAID)
    10004485881
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
ページトップへ