A Unique Chelating Effect of Sc(OTf)_3 to Organofluorine Compounds

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著者

    • KAJIRO Hiroshi
    • Research Laboratory of Resources Utilization, Tokyo Institute of Technology
    • MORI Atsunori
    • Research Laboratory of Resources Utilization, Tokyo Institute of Technology
    • NISHIHARA Yasushi
    • Research Laboratory of Resources Utilization, Tokyo Institute of Technology
    • HIYAMA Tamejiro
    • Research Laboratory of Resources Utilization, Tokyo Institute of Technology

抄録

The scandium trifluoromethanesulfonate-catalyzed cleavage of acetate bearing two or three fluorine atoms at a position β to an acetoxy group proceeds exceptionally rapidly. The high efficiency of the hydrolysis is caused by a chelating effect of scandium with the fluorine atoms and an acetate moiety.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1999(6), 459-460, 1999-06-05 

    The Chemical Society of Japan

参考文献:  24件

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各種コード

  • NII論文ID(NAID)
    10004485881
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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