Synthesis of Tetrahydroindole Derivatives Using Titanium-Nitrogen Complexes Derived from Molecular Nitrogen

• Akashi Masaya

  Graduate School of Pharmaceutical Sciences, Hokkaido University

• Nishida Mayumi

  Graduate School of Pharmaceutical Sciences, Hokkaido University

• Mori Miwako

  Graduate School of Pharmaceutical Sciences, Hokkaido University

抄録

Synthesis of tetrahydroindole derivatives was realized from keto-alkyne using titanium-nitrogen complexes generated from Ti(OiPr)₄, Li, and TMSCl. In this reaction, the electron-withdrawing group on the alkyne gave a good yield, and keto-alkynes having an aromatic ring on the alkyne also gave tetrahydroindole derivatives in good to moderate yields.

収録刊行物

• Chemistry Letters

  Chemistry Letters 28 (6), 465-466, 1999

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204576706176
• NII論文ID: 10004485925
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.1999.465
• COI: 1:CAS:528:DyaK1MXjs1OjtL0%3D
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/28/6/465/56076974/cl.1999.465.pdf
• 本文言語コード: en
• データソース種別:
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  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可