Electronic Factors in the C - Glycosidation with Silylacetylene

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著者

    • ISOBE Minoru
    • Laboratory of Organic Chemistry, School of Bioagricultural Sciences, Nagoya University
    • SAEENG Rungnapha
    • Laboratory of Organic Chemistry, School of Bioagricultural Sciences, Nagoya University
    • NISHIZAWA Rena
    • Laboratory of Organic Chemistry, School of Bioagricultural Sciences, Nagoya University
    • KONOBE Masato
    • Laboratory of Organic Chemistry, School of Bioagricultural Sciences, Nagoya University
    • NISHIKAWA Toshio
    • Laboratory of Organic Chemistry, School of Bioagricultural Sciences, Nagoya University

抄録

Two kinds of electronic factors have been clarified to control the reactivity in alkynylation of glycals with silylacetylenes. One is that the reactivity of nucleophile silylpropargyl alcohol derivative largely depends on the protecting group. The second factor is found in the similar electrophiles as oxocarbenium intermediates that were generated from glucals or galactals. Diminished reactivity was found with the 4-axial substituents such as acetoxy or methoxy group.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(6), 467-468, 1999-06-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004485962
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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