Mixed Phthalocyaninato - Porphyrinato Europium(III) Triple - decker Sandwich Complexes Containing a Conjugated Dimeric Porphyrin Ligand
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The first examples of triple-decker europium(III) sandwich complexes containing bis(octaethylporphyrinyl)butadiyne and phthalocyanine have been prepared by condensation of NiOEP-C<SUB>4</SUB>-OEPH<SUB>2</SUB>(H<SUB>2</SUB><B>1</B>) and Li<SUB>2</SUB>Pc with Eu(acac)<SUB>3</SUB>·H<SUB>2</SUB>O. The complexes (Pc)Eu(<B>1</B>)Eu(Pc) and (<B>1</B>)Eu(Pc)Eu(Pc) were characterized by NMR, IR, Raman, UV-vis, and mass spectra.
- Chemistry Letters
Chemistry Letters 1999(6), 483-484, 1999-06-05
The Chemical Society of Japan