Syntheses of Diruthenaborane Clusters, [[Cp^*Ru(μ - H)}_2B_3H_7], [{(Cp^*Ru)_2(μ - H)}B_4H_9], and [(Cp^*Ru)_2(μ - H)(PMe_3)(μ - η^4 - B_2H_5)]

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著者

    • KAWANO Yasuro
    • Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo
    • MATSUMOTO Hideyuki
    • Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo
    • SHIMOI Mamoru
    • Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo

抄録

A diruthenapentaborane cluster [{Cp<SUP>*</SUP>Ru(μ-H)}<SUB>2</SUB>B<SUB>3</SUB>H<SUB>7</SUB>] (<B>1</B>) was synthesized by the reaction of [Cp<SUP>*</SUP>RuCl]<SUB>4</SUB> with BH<SUB>3</SUB>·THF. Compound <B>1</B> undergoes cluster expansion by further interaction with BH<SUB>3</SUB>·THF to give [{(Cp<SUP>*</SUP>Ru)<SUB>2</SUB>(μ-H)}B<SUB>4</SUB>H<SUB>9</SUB>] (<B>2</B>). Reaction of <B>1</B> with PMe<SUB>3</SUB> leads to degradation of the cluster framework to give [{(Cp<SUP>*</SUP>Ru)<SUB>2</SUB>(μ-H)}(PMe<SUB>3</SUB>)(μ-η<SUP>4</SUP>-B<SUB>2</SUB>H<SUB>5</SUB>)] (<B>3</B>).

収録刊行物

  • Chemistry letters  

    Chemistry letters 1999(6), 489-490, 1999-06-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004486147
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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