Syntheses of Diruthenaborane Clusters, [[Cp^*Ru(μ - H)}_2B_3H_7], [{(Cp^*Ru)_2(μ - H)}B_4H_9], and [(Cp^*Ru)_2(μ - H)(PMe_3)(μ - η^4 - B_2H_5)]

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著者

    • KAWANO Yasuro
    • Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo
    • MATSUMOTO Hideyuki
    • Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo
    • SHIMOI Mamoru
    • Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo

抄録

A diruthenapentaborane cluster [{Cp<SUP>*</SUP>Ru(μ-H)}<SUB>2</SUB>B<SUB>3</SUB>H<SUB>7</SUB>] (<B>1</B>) was synthesized by the reaction of [Cp<SUP>*</SUP>RuCl]<SUB>4</SUB> with BH<SUB>3</SUB>·THF. Compound <B>1</B> undergoes cluster expansion by further interaction with BH<SUB>3</SUB>·THF to give [{(Cp<SUP>*</SUP>Ru)<SUB>2</SUB>(μ-H)}B<SUB>4</SUB>H<SUB>9</SUB>] (<B>2</B>). Reaction of <B>1</B> with PMe<SUB>3</SUB> leads to degradation of the cluster framework to give [{(Cp<SUP>*</SUP>Ru)<SUB>2</SUB>(μ-H)}(PMe<SUB>3</SUB>)(μ-η<SUP>4</SUP>-B<SUB>2</SUB>H<SUB>5</SUB>)] (<B>3</B>).

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(6), 489-490, 1999-06-05

    The Chemical Society of Japan

参考文献:  19件中 1-19件 を表示

  • <no title>

    BARTON L.

    Comprehensive Organometallic Chemistry II 1, 275-372, 1995

    被引用文献1件

  • <no title>

    NISHIHARA Y.

    Organometallics 13, 4510, 1994

    被引用文献2件

  • <no title>

    HO J.

    J. Am. Chem. Soc. 117, 10292, 1995

    被引用文献1件

  • <no title>

    ALDRIDGE S.

    J. Am. Chem. Soc. 120, 2586, 1998

    被引用文献1件

  • <no title>

    WELLER A. S.

    J. Chem. Soc., Chem. Commun. 1998, 1787

    被引用文献1件

  • <no title>

    WELLER A. S.

    J. Am. Chem. Soc. 120, 8283, 1998

    被引用文献1件

  • <no title>

    LEI X.

    Organometallics 17, 1558, 1998

    被引用文献1件

  • <no title>

    BOULD J.

    Organometallics 14, 5138, 1995

    被引用文献1件

  • <no title>

    ANDERSEN E. L.

    J. Am. Chem. Soc. 101, 4390, 1979

    被引用文献1件

  • <no title>

    BROWN M.

    J. Organomet. Chem. 309, C67, 1986

    被引用文献1件

  • <no title>

    BOULD J.

    J. Organomet. Chem. 249, 11, 1983

    被引用文献1件

  • <no title>

    KAWANO Y.

    Chem. Lett. 1998, 935

    被引用文献1件

  • <no title>

    FAGAN P. J.

    J. Am. Chem. Soc. 111, 1698, 1989

    被引用文献7件

  • <no title>

    LEI X.

    J. Am. Chem. Soc. 121, 1275, 1999

    被引用文献2件

  • <no title>

    TILLEY T. D.

    Organometallics 3, 274, 1984

    被引用文献6件

  • <no title>

    CHIPPERFIELD A. K.

    J. Organomet. Chem. 384, C38, 1990

    被引用文献1件

  • <no title>

    HOUSCROFT C. E.

    J. Chem. Soc., Dalton Trans. 1993, 2727

    被引用文献1件

  • <no title>

    FEILONG J.

    J. Organomet. Chem. 348, C22, 1988

    被引用文献1件

  • <no title>

    AHMAD R.

    J. Chem. Soc., Dalton Trans. 1986, 2433

    被引用文献1件

各種コード

  • NII論文ID(NAID)
    10004486147
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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