A Convenient Synthesis of a Ru(bpy)_3 - based Catenane - type Triad and Its Incorporation into a Protein Scaffold

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著者

    • HU Yi-Zhen
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
    • TSUKIJI Shinya
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
    • SHINKAI Seiji
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
    • HAMACHI Itaru
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University

抄録

A catenated heme cofactor consisting of a donor (protoheme), a sensitizer (Ru(2,2′-bipyridine)<SUB>3</SUB>) and an acceptor (cyclobis(paraquat-<I>p</I>-phenylene) was prepared by stepwise coordination, followed by iron-insersion. Reconstitution of apo-myoglobin with this cofactor afforded a protein-based, noncovalently-linked photosynthetic triad.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(6), 517-518, 1999-06-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004486358
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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