Structures of Four Types of Novel High - Valent Manganese Complexes Obtained by the Reactions of KMnO_4 with Tridentate Schiff Base Ligands

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著者

    • ASADA Hideyuki
    • Department of Materials Chemistry, Faculty of Science and Technology, Ryukoku University
    • OZEKI Minoru
    • Department of Materials Chemistry, Faculty of Science and Technology, Ryukoku University
    • FUJIWARA Manabu
    • Department of Materials Chemistry, Faculty of Science and Technology, Ryukoku University
    • MATSUSHITA Takayuki
    • Department of Materials Chemistry, Faculty of Science and Technology, Ryukoku University

抄録

Four types of novel manganese complexes, Mn<SUP>IV</SUP> (<I>N</I>-EtO-sal)<SUB>2</SUB>, Mn<SUP>III</SUP>(<I>N</I>-PhO-sal)(L), [Mn<SUP>IV</SUP>(5,6-Benzo-L)<SUB>2</SUB> (<I>μ</I>-O)<SUB>2</SUB>]<SUB>2</SUB>, and Mn<SUP>III</SUP>(L-4-Me)<SUB>3</SUB> have been found to be obtained by the reactions of KMnO<SUB>4</SUB> with tridentate Schiff base ligands (<I>N</I>-EtOH-salH, <I>N</I>-PhOH-salH and their derivatives) in dry MeCN, where <I>N</I>-EtOH-salH, <I>N</I>-PhOH-salH, LH, 5,6-Benzo-LH, and L-4-MeH denote <I>N</I>-2-hydroxyethyl-salicylideneamine, <I>N</I>-2-hydroxyphenyl-salicylideneamine, 2-(2-hydroxyphenyl)-benzoxazole, 2-(2-hydroxynaphthyl)-benzoxazole, and 2-(2-hydroxyphenyl)-5-methylbenzoxazole, respectively.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1999(6), 525-526, 1999-06-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004486422
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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