A Facile Synthesis of Optically Active 1,1,1 - Trifluoro - 3 - alkyn - 2 - ols by Stereospecific Substitution of Optically Active 1 - Benzyloxy - 2,2,2 - trifluoroethyl Tosylate with Lithium Alkynyltriethylaluminates

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Optically active 1-benzyloxy-2,2,2-trifluoroethyl tosylate reacts with various lithium alkynyltriethylaluminates to give optically active 2-benzyloxy-1,1,1-trifluoro-3-alkynes selectively and stereospecifically with inversion of configuration. Thus, the reaction provides with a novel method for the preparation of various optically active 1,1,1-trifluoro-3-alkyn-2-ols.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(6), 529-530, 1999-06-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004486441
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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