Influence of Sulfur Content and Temperature on the Carbon Boil and CO Generation in Fe-C-S Drops.

  • Gao Kevin
    School of Materials Science and Engineering, The University of New South Wales
  • Sahajwalla Veena
    School of Materials Science and Engineering, The University of New South Wales
  • Sun Haiping
    School of Materials Science and Engineering, The University of New South Wales
  • Wheatley Charles
    BHP BOS/Slab making division
  • Dry Rod
    Rio Tinto HIsmelt <sup>®</sup> Corporation

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Carbon boil in liquid iron has been studied as a function of some key parameters such as sulfur content (0.005–0.4%) and temperature (1370–1450°C) in a horizontal tube furnace. The metal–gas reactions and their time dependence, that is their dynamic nature, were observed in-situ at the temperature of interest. Experiments of Fe–C–S drops were also conducted in a vertical super-kanthal tube furnace to permit rapid quenching of metal drops and their subsequent analysis. The starting time of carbon boil phenomenon was determined using a CCD camera coupled with a time/date generator connected to a video recorder. The initiation time of carbon boil was in the range ∼5 and ∼20 sec under the conditions in this study. Mechanism for carbon boil has been proposed.

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