真空蒸着法による有機・無機ナノ複合体の研究-フタロシアニンと銅の共蒸着における錯化反応の収率制御- Study on Organic-Inorganic Nano-Composite Fabricated by Vacuum Deposition Method-Control of the Yield in the Complex Formation Reaction by the Simultaneous Evaporation of Copper and Phthalocyanine-
Co-deposition films of copper (Cu) and metal free phthalocyanine (Pc) (Cu*Pc) were prepared by evaporating Cu and Pc simultaneously in vacuum. From the visible absorption spectra of dilute 1-chloronaphthalene solutions of the Cu*Pc samples, the formation of metal-phthalocyanine complex (CuPc) was confirmed in the samples. The yield of CuPc increases with increase of the deposition rate of Cu component at the constant rate of Pc component. Accordingly, on Pc component, a condition for 100% yield of CuPc formation was determinated. It was also found that each fraction of Pc, CuPc and Cu in the co-deposition film could be also controlled correctly.
真空 43(8), 790-794, 2000-08-20
The Vacuum Society of Japan