水素結合をもつ硫化水素固体の高圧相 [in Japanese] High-pressure Phase Studies of Solid Hydrogen Sulfide having Hydrogen Bonds [in Japanese]
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This article reviews recent developments in high-pressure phase studies of H<SUB>2</SUB>S by Raman scattering, x-ray and neutron diffractions, FT infrared absorption, and first-principles calculation. At room temperature, solid H<SUB>2</SUB>S shows many phase transitions under high pressures; - I - (8 GPa) -I'- (11 GPa) - IV - (30 GPa) - V - (46 GPa) - VI -. The characteristic features of each phase transition are presented and discussed by considering the behaviors of hydrogen bondings and molecular rotations.
- The Review of High Pressure Science and Technology
The Review of High Pressure Science and Technology 10(1), 18-25, 2000-02-20
The Japan Society of High Pressure Science and Technology