Hydrogen Bonding. High-pressure Phase Studies of Solid Hydrogen Sulfide having Hydrogen Bonds.

• SHIMIZU Hiroyasu

  Department of Electrical and Electronic Engineering, Gifu University

Bibliographic Information

Other Title

• 水素結合　　水素結合をもつ硫化水素固体の高圧相
• スイソ ケツゴウ オ モツ リュウカ スイソ コタイ ノ コウアツソウ

Abstract

This article reviews recent developments in high-pressure phase studies of H₂S by Raman scattering, x-ray and neutron diffractions, FT infrared absorption, and first-principles calculation. At room temperature, solid H₂S shows many phase transitions under high pressures; - I - (8 GPa) -I'- (11 GPa) - IV - (30 GPa) - V - (46 GPa) - VI -. The characteristic features of each phase transition are presented and discussed by considering the behaviors of hydrogen bondings and molecular rotations.

Journal

• The Review of High Pressure Science and Technology

  The Review of High Pressure Science and Technology 10 (1), 18-25, 2000

  The Japan Society of High Pressure Science and Technology

Keywords

• DAC
• hydrogen sulfide
• Raman scattering
• x-ray diffraction
• neutron diffraction
• infrared absorption
• firstprinciples calculation
• phase transition
• hydrogen bond
• molecular rotation
• molecular dissociation

Details

• CRID: 1390282679358440704
• NII Article ID: 10004668461
• NII Book ID: AN10452913
• DOI: 10.4131/jshpreview.10.18
• COI: 1:CAS:528:DC%2BD3cXis1aisLg%3D
• ISSN: 13481940
• ISSN: 0917639X
• ISSN: http://id.crossref.org/issn/0917639X
• NDL BIB ID: 5285201
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I5285201
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed