分子結晶における電子-プロトン連動と機能性 [in Japanese] Electron-proton Cooperation in Molecular Crystals [in Japanese]
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The cooperation of electron and proton in organic systems has a large potentiality for the creation of new molecular functions in molecular crystals. In this article, the electron-proton-cooperation in charge transfer crystals is reviewed, particularly focusing on the it spectroscopy of the phase transition in quinhydrone charge-transfer crystals under high pressures. As an example of the electron-proton cooperation at ambient pressure, the metal-insulator phase transition observed in [Pd (H<SUB>2-x</SUB>EDAG) (HEDAG) ]TCNQ (EDAG= ethylenediamino-glyoxime, x = ca. 0. 7) is reported.
- The Review of High Pressure Science and Technology
The Review of High Pressure Science and Technology 10(1), 42-49, 2000-02-20
The Japan Society of High Pressure Science and Technology