超臨界重合の工業化に想う-高圧重合の歴史から眺めたテフロン製造プロセス- [in Japanese] Industrialization of Supercritical High Pressure Polymerization in Teflon Production [in Japanese]
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The historical development of polymerization under high pressure has been reviewed and the possibility of an industrial application of high pressure polymerization has been discussed in our previous works on radical polymerization at high pressure. Taking recent environmental concerns into consideration and the significant advancement in the technology of high temperature and high pressure, the synthesis of fluoropolymers in supercritical carbon dioxide, especially DeSimone's process, is discussed considering the chemical kinetics at the critical point with emphasis on supercritical carbon dioxide as an excellent reaction media.
- The Review of High Pressure Science and Technology
The Review of High Pressure Science and Technology 10(1), 50-55, 2000-02-20
The Japan Society of High Pressure Science and Technology