液体リンの1次相転移 A First-Order Phase Transition in Liquid Phosphorus
In this article, a recent discovery of a liquid-liquid phase transition in phosphorus is reviewed. By an in situ X-ray diffraction method, we have observed an abrupt pressure-induced structural change between a low-pressure molecular liquid and a high-pressure polymeric liquid at about 1 GPa. Experimental results strongly support that it is a first-order transition between two thermodynamically stable liquid phases. This is the first in-situ observation of such a transition in a liquid of pure substance.
- 高圧力の科学と技術 = The Review of high pressure science and technology
高圧力の科学と技術 = The Review of high pressure science and technology 10(3), 221-227, 2000-08-20
The Japan Society of High Pressure Science and Technology