Stereo- and Regio-Control of 1, 3-Dipolar Cycloaddition Reactions by the Aid of Lewis Acid Catalysts—Nitrone and aci-Nitro Compound Cycloadditions—

  • KANEMASA Shuji
    Institute of Advanced Material Study, Kyushu University; 6-1 Kasugakoen, Kasuga-shi 816-8580 Japan

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Other Title
  • ルイス酸触媒による1,3-双極付加環化反応の立体およびレギオ制御<BR>—ニトロンおよびaci-ニトロ化合物の付加環化反応—
  • ルイス酸触媒による1,3-双極付加環化反応の立体およびレギオ制御--ニトロンおよびaci-ニトロ化合物の付加環化反応
  • ルイス サン ショクバイ ニ ヨル 1 3 ソウキョク フカカンカ ハンノウ ノ リッタイ オヨビ レギオ セイギョ ニトロン オヨビ aci ニトロ カゴウブツ ノ フカカンカ ハンノウ
  • Stereo- and Regio-Control of 1, 3-Dipolar Cycloaddition Reactions by the Aid of Lewis Acid Catalysts&mdash;Nitrone and aci-Nitro Compound Cycloadditions&mdash;

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Abstract

Much attention is now focussed on the stereo- and regiocontrol of 1, 3-dipolar cycloaddition reactions by the aid of a Lewis acid catalyst. The report of catalyzed asymmetric nitrone cycloadditions has triggered the acceleration of research development of this field. This review describes the Lewis acid-catalyzed nitrone cycloadditions to electron-deficient alkenes, the Lewis acid-catalyzed nitrone cycloadditions to electron-rich alkenes such as allylic alcohols, and asymmetric nitrone and aci-nitro compound cycloadditions to electron-deficient alkenes catalyzed by DBFOX/Ph metal complexes.

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