1-ナフチルアラニルグリシン誘導体の分子内蛍光消光 Intramolecular Fluorescence Quenching in 1-Naphthylalanylglycine Derivative

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With the aid of stationary and time-resolved fluorescence spectroscopy, we investigated solvent, viscosity and temperature effects on the rate of the intramolecular fluorescence quenching process in 1-naphthylalanylglycine derivative having 1-naphthyl(electron acceptor) and diethylamino(electron donor) groups. By comparing with kinetic and thermodynamic parameters for the fluorescence quenching process of the corresponding 1-naphthylalanine derivative, it was shown that in addition to the hydrogen-bonding solvation in the locally excited singlet state of this derivative and the stability of the exciplex intermediate, the average distance between the electron acceptor and donor groups is also a factor in controlling the charge-transfer rate.

収録刊行物

  • 日本化学会誌 : 化学と工業化学 = Journal of the Chemical Society of Japan : chemistry and industrial chemistry  

    日本化学会誌 : 化学と工業化学 = Journal of the Chemical Society of Japan : chemistry and industrial chemistry 2000(7), 511-516, 2000-07-10 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004688700
  • NII書誌ID(NCID)
    AN00186595
  • 本文言語コード
    JPN
  • 資料種別
    NOT
  • ISSN
    03694577
  • NDL 記事登録ID
    5400576
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z17-659
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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