Intramolecular Fluorescence Quenching in 1-Naphthylalanylglycine Derivative
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- OZAWA Kiyofumi
- Department of Applied Chemistry, Faculty of Engineering, Kanagawa University; Kanagawa-ku, Yokohama-shi 221-8686 Japan
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- MIYOSHI Kenichiro
- Department of Applied Chemistry, Faculty of Engineering, Kanagawa University; Kanagawa-ku, Yokohama-shi 221-8686 Japan
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- KUBO Kanji
- Department of Applied Chemistry, Faculty of Engineering, Kanagawa University; Kanagawa-ku, Yokohama-shi 221-8686 Japan Institute of Advanced Material Study, Kyushu University; Kasuga-koen, Kasuga-shi 816-0811 Japan
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- IGARASHI Tetsutaro
- Department of Applied Chemistry, Faculty of Engineering, Kanagawa University; Kanagawa-ku, Yokohama-shi 221-8686 Japan
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- SAKURAI Tadamitsu
- Department of Applied Chemistry, Faculty of Engineering, Kanagawa University; Kanagawa-ku, Yokohama-shi 221-8686 Japan
Bibliographic Information
- Other Title
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- 1-ナフチルアラニルグリシン誘導体の分子内蛍光消光
- 1 ナフチルアラニルグリシン ユウドウタイ ノ ブンシ ナイ ケイコウ ショウコウ
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Abstract
With the aid of stationary and time-resolved fluorescence spectroscopy, we investigated solvent, viscosity and temperature effects on the rate of the intramolecular fluorescence quenching process in 1-naphthylalanylglycine derivative having 1-naphthyl(electron acceptor) and diethylamino(electron donor) groups. By comparing with kinetic and thermodynamic parameters for the fluorescence quenching process of the corresponding 1-naphthylalanine derivative, it was shown that in addition to the hydrogen-bonding solvation in the locally excited singlet state of this derivative and the stability of the exciplex intermediate, the average distance between the electron acceptor and donor groups is also a factor in controlling the charge-transfer rate.
Journal
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- NIPPON KAGAKU KAISHI
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NIPPON KAGAKU KAISHI 2000 (7), 511-516, 2000
The Chemical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001204390439296
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- NII Article ID
- 10004688700
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- NII Book ID
- AN00186595
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- COI
- 1:CAS:528:DC%2BD3cXltlylsr8%3D
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- ISSN
- 21850925
- 03694577
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- NDL BIB ID
- 5400576
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed