Competition between Electroauxiliaries. Selective Electrochemical Oxidation of Heteroatom Compounds Having Silicon and Tin on the Same Carbon

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著者

    • YOSHIDA Jun-ichi
    • Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
    • WATANABE Mitsuru
    • Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
    • TOSHIOKA Hideaki
    • Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
    • IMAGAWA Masayuki
    • Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
    • SUGA Seiji
    • Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

抄録

The selective electrochemical oxidation of heteroatom compounds having two different types of electroauxiliaries, i.e. silicon and tin on the same α carbon has been achieved. The C-Sn bond was cleaved selectively and a nucleophile was introduced. The second oxidation of the compound thus obtained gave rise to the cleavage of the C-Si bond and the introduction of a second nucleophile. The present study indicates the feasibility of the redox potential based strategies using electroauxiliaries.

収録刊行物

  • Chemistry letters

    Chemistry letters 1998(10), 1011-1012, 1998-10-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004700013
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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